Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon

Iwao Ojima; Yoichiro Nagai

doi:10.1016/S0022-328X(00)86579-1

Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon

Iwao Ojima
, Yoichiro Nagai

Chemistry

Gunma University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a Rh^I complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol.

Original language	English
Pages (from-to)	C42-C44
Journal	Journal of Organometallic Chemistry
Volume	57
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)86579-1
State	Published - Sep 1 1973

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title = "Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon",

abstract = "Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a RhI complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol.",

author = "Iwao Ojima and Yoichiro Nagai",

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AU - Ojima, Iwao

AU - Nagai, Yoichiro

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Y1 - 1973/9/1

N2 - Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a RhI complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol.

AB - Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a RhI complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol.

UR - https://www.scopus.com/pages/publications/4243844161

U2 - 10.1016/S0022-328X(00)86579-1

DO - 10.1016/S0022-328X(00)86579-1

M3 - Article

AN - SCOPUS:4243844161

SN - 0022-328X

VL - 57

SP - C42-C44

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon

Abstract

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