Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching

J. Carretero-González; R. Verdejo; E. P. Giannelis; S. Toki; B. S. Hsiao; M. A. López-Manchado

Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching

J. Carretero-González
, R. Verdejo
, E. P. Giannelis
, S. Toki
, B. S. Hsiao
, M. A. López-Manchado

Chemistry

CSIC - Instituto de Ciencia y Tecnologia de Polimeros (ICTP)
Cornell University
Stony Brook University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The inclusion of clay nanoparticles (nanoclay) in cross-linked natural rubber (NR) induces an early promotion and enhancement on crystallization under uniaxial deformation. We evaluate and monitor the molecular structure of the polymer network and its changes during elongation by using in-situ synchrotron radiation. Nanoclay introduces an increase of the crystalline content and a dual crystallization mechanism related to the alignment of the nanoparticles during stretching. This study could be the starting point on the designing of a new generation of elastomers materials without the trade-off exhibited in conventional rubber composites.

Original language	English
Title of host publication	Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008
Pages	838-839
Number of pages	2
State	Published - 2008
Event	2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008 - Quebec City, QC, United States Duration: Jun 1 2008 → Jun 5 2008

Publication series

Name	Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008
Volume	1

Conference

Conference	2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008
Country/Territory	United States
City	Quebec City, QC
Period	06/1/08 → 06/5/08

Keywords

Crystallization
Nanoclay
Natural rubber

Cite this

Carretero-González, J., Verdejo, R., Giannelis, E. P., Toki, S., Hsiao, B. S., & López-Manchado, M. A. (2008). Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching. In Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008 (pp. 838-839). (Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008; Vol. 1).

Carretero-González, J. ; Verdejo, R. ; Giannelis, E. P. et al. / Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching. Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. 2008. pp. 838-839 (Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008).

@inproceedings{f2756f4b9c9c45449cdd1de6abc52222,

title = "Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching",

abstract = "The inclusion of clay nanoparticles (nanoclay) in cross-linked natural rubber (NR) induces an early promotion and enhancement on crystallization under uniaxial deformation. We evaluate and monitor the molecular structure of the polymer network and its changes during elongation by using in-situ synchrotron radiation. Nanoclay introduces an increase of the crystalline content and a dual crystallization mechanism related to the alignment of the nanoparticles during stretching. This study could be the starting point on the designing of a new generation of elastomers materials without the trade-off exhibited in conventional rubber composites.",

keywords = "Crystallization, Nanoclay, Natural rubber",

author = "J. Carretero-Gonz{\'a}lez and R. Verdejo and Giannelis, \{E. P.\} and S. Toki and Hsiao, \{B. S.\} and L{\'o}pez-Manchado, \{M. A.\}",

year = "2008",

language = "English",

isbn = "9781420085075",

series = "Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008",

pages = "838--839",

booktitle = "Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008",

note = "2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008 ; Conference date: 01-06-2008 Through 05-06-2008",

}

Carretero-González, J, Verdejo, R, Giannelis, EP, Toki, S, Hsiao, BS & López-Manchado, MA 2008, Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching. in Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008, vol. 1, pp. 838-839, 2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008, Quebec City, QC, United States, 06/1/08.

Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching. / Carretero-González, J.; Verdejo, R.; Giannelis, E. P. et al.
Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. 2008. p. 838-839 (Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008; Vol. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching

AU - Carretero-González, J.

AU - Verdejo, R.

AU - Giannelis, E. P.

AU - Toki, S.

AU - Hsiao, B. S.

AU - López-Manchado, M. A.

PY - 2008

Y1 - 2008

N2 - The inclusion of clay nanoparticles (nanoclay) in cross-linked natural rubber (NR) induces an early promotion and enhancement on crystallization under uniaxial deformation. We evaluate and monitor the molecular structure of the polymer network and its changes during elongation by using in-situ synchrotron radiation. Nanoclay introduces an increase of the crystalline content and a dual crystallization mechanism related to the alignment of the nanoparticles during stretching. This study could be the starting point on the designing of a new generation of elastomers materials without the trade-off exhibited in conventional rubber composites.

AB - The inclusion of clay nanoparticles (nanoclay) in cross-linked natural rubber (NR) induces an early promotion and enhancement on crystallization under uniaxial deformation. We evaluate and monitor the molecular structure of the polymer network and its changes during elongation by using in-situ synchrotron radiation. Nanoclay introduces an increase of the crystalline content and a dual crystallization mechanism related to the alignment of the nanoparticles during stretching. This study could be the starting point on the designing of a new generation of elastomers materials without the trade-off exhibited in conventional rubber composites.

KW - Crystallization

KW - Nanoclay

KW - Natural rubber

UR - https://www.scopus.com/pages/publications/53349096683

M3 - Conference contribution

AN - SCOPUS:53349096683

SN - 9781420085075

SN - 9781420085037

T3 - Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008

SP - 838

EP - 839

BT - Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008

T2 - 2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008

Y2 - 1 June 2008 through 5 June 2008

ER -

Carretero-González J, Verdejo R, Giannelis EP, Toki S, Hsiao BS, López-Manchado MA. Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching. In Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. 2008. p. 838-839. (Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008).

Real-time crystallization of organoclay nanoparticle filled natural rubber under stretching

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Keywords

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