Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

Wen Zhang; Debasis Banerjee; Jian Liu; Herbert T. Schaef; Jarrod V. Crum; Carlos A. Fernandez; Ravi K. Kukkadapu; Zimin Nie; Satish K. Nune; Radha K. Motkuri; Karena W. Chapman; Mark H. Engelhard; James C. Hayes; Kurt L. Silvers; Rajamani Krishna; B. Peter McGrail; Jun Liu; Praveen K. Thallapally

doi:10.1002/adma.201600259

Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

Wen Zhang
, Debasis Banerjee
, Jian Liu
, Herbert T. Schaef
, Jarrod V. Crum
, Carlos A. Fernandez
, Ravi K. Kukkadapu
, Zimin Nie
, Satish K. Nune
, Radha K. Motkuri
, Karena W. Chapman
, Mark H. Engelhard
, James C. Hayes
, Kurt L. Silvers
, Rajamani Krishna
, B. Peter McGrail
, Jun Liu
, Praveen K. Thallapally

Chemistry

Pacific Northwest National Laboratory
Environmental Molecular Sciences Laboratory
University of Amsterdam

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

A redox-active metal-organic composite material shows improved and selective O₂ adsorption over N₂ with respect to individual components (MIL-101 and ferrocene). The O₂ sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.

Original language	English
Pages (from-to)	3572-3577
Number of pages	6
Journal	Advanced Materials
Volume	28
Issue number	18
DOIs	https://doi.org/10.1002/adma.201600259
State	Published - May 11 2016

Keywords

composite materials
metal-organic frameworks
oxygen sensors
oxygen separation
redox-active

Access to Document

10.1002/adma.201600259

Cite this

Zhang, W., Banerjee, D., Liu, J., Schaef, H. T., Crum, J. V., Fernandez, C. A., Kukkadapu, R. K., Nie, Z., Nune, S. K., Motkuri, R. K., Chapman, K. W., Engelhard, M. H., Hayes, J. C., Silvers, K. L., Krishna, R., McGrail, B. P., Liu, J., & Thallapally, P. K. (2016). Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications. Advanced Materials, 28(18), 3572-3577. https://doi.org/10.1002/adma.201600259

@article{33377983d60d4517995f7261bb2dddcb,

title = "Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications",

abstract = "A redox-active metal-organic composite material shows improved and selective O2 adsorption over N2 with respect to individual components (MIL-101 and ferrocene). The O2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.",

keywords = "composite materials, metal-organic frameworks, oxygen sensors, oxygen separation, redox-active",

author = "Wen Zhang and Debasis Banerjee and Jian Liu and Schaef, \{Herbert T.\} and Crum, \{Jarrod V.\} and Fernandez, \{Carlos A.\} and Kukkadapu, \{Ravi K.\} and Zimin Nie and Nune, \{Satish K.\} and Motkuri, \{Radha K.\} and Chapman, \{Karena W.\} and Engelhard, \{Mark H.\} and Hayes, \{James C.\} and Silvers, \{Kurt L.\} and Rajamani Krishna and McGrail, \{B. Peter\} and Jun Liu and Thallapally, \{Praveen K.\}",

note = "Publisher Copyright: {\textcopyright} 2016 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2016",

month = may,

day = "11",

doi = "10.1002/adma.201600259",

language = "English",

volume = "28",

pages = "3572--3577",

journal = "Advanced Materials",

issn = "0935-9648",

number = "18",

}

Zhang, W, Banerjee, D, Liu, J, Schaef, HT, Crum, JV, Fernandez, CA, Kukkadapu, RK, Nie, Z, Nune, SK, Motkuri, RK, Chapman, KW, Engelhard, MH, Hayes, JC, Silvers, KL, Krishna, R, McGrail, BP, Liu, J & Thallapally, PK 2016, 'Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications', Advanced Materials, vol. 28, no. 18, pp. 3572-3577. https://doi.org/10.1002/adma.201600259

TY - JOUR

T1 - Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

AU - Zhang, Wen

AU - Banerjee, Debasis

AU - Liu, Jian

AU - Schaef, Herbert T.

AU - Crum, Jarrod V.

AU - Fernandez, Carlos A.

AU - Kukkadapu, Ravi K.

AU - Nie, Zimin

AU - Nune, Satish K.

AU - Motkuri, Radha K.

AU - Chapman, Karena W.

AU - Engelhard, Mark H.

AU - Hayes, James C.

AU - Silvers, Kurt L.

AU - Krishna, Rajamani

AU - McGrail, B. Peter

AU - Liu, Jun

AU - Thallapally, Praveen K.

PY - 2016/5/11

Y1 - 2016/5/11

N2 - A redox-active metal-organic composite material shows improved and selective O2 adsorption over N2 with respect to individual components (MIL-101 and ferrocene). The O2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.

AB - A redox-active metal-organic composite material shows improved and selective O2 adsorption over N2 with respect to individual components (MIL-101 and ferrocene). The O2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.

KW - composite materials

KW - metal-organic frameworks

KW - oxygen sensors

KW - oxygen separation

KW - redox-active

UR - https://www.scopus.com/pages/publications/84959935017

U2 - 10.1002/adma.201600259

DO - 10.1002/adma.201600259

M3 - Article

AN - SCOPUS:84959935017

SN - 0935-9648

VL - 28

SP - 3572

EP - 3577

JO - Advanced Materials

JF - Advanced Materials

IS - 18

ER -

Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this