Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

Hisanori Nagatomi; Leighanne C. Gallington; Subhadip Goswami; Jiaxin Duan; Karena W. Chapman; Nobuhiro Yanai; Nobuo Kimizuka; Omar K. Farha; Joseph T. Hupp

doi:10.1021/acsomega.0c04823

Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

Hisanori Nagatomi
, Leighanne C. Gallington
, Subhadip Goswami
, Jiaxin Duan
, Karena W. Chapman
, Nobuhiro Yanai
, Nobuo Kimizuka
, Omar K. Farha
, Joseph T. Hupp

Chemistry

Northwestern University
Kyushu University
United States Department of Energy
Japan Science and Technology Agency

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr₆ nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex Ru^II(bpy)₂(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

Original language	English
Pages (from-to)	30299-30305
Number of pages	7
Journal	ACS Omega
Volume	5
Issue number	46
DOIs	https://doi.org/10.1021/acsomega.0c04823
State	Published - Nov 24 2020

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title = "Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)",

abstract = "Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.",

author = "Hisanori Nagatomi and Gallington, \{Leighanne C.\} and Subhadip Goswami and Jiaxin Duan and Chapman, \{Karena W.\} and Nobuhiro Yanai and Nobuo Kimizuka and Farha, \{Omar K.\} and Hupp, \{Joseph T.\}",

year = "2020",

month = nov,

day = "24",

doi = "10.1021/acsomega.0c04823",

language = "English",

volume = "5",

pages = "30299--30305",

journal = "ACS Omega",

issn = "2470-1343",

number = "46",

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TY - JOUR

T1 - Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

AU - Nagatomi, Hisanori

AU - Gallington, Leighanne C.

AU - Goswami, Subhadip

AU - Duan, Jiaxin

AU - Chapman, Karena W.

AU - Yanai, Nobuhiro

AU - Kimizuka, Nobuo

AU - Farha, Omar K.

AU - Hupp, Joseph T.

PY - 2020/11/24

Y1 - 2020/11/24

N2 - Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

AB - Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

UR - https://www.scopus.com/pages/publications/85096831363

U2 - 10.1021/acsomega.0c04823

DO - 10.1021/acsomega.0c04823

M3 - Article

AN - SCOPUS:85096831363

SN - 2470-1343

VL - 5

SP - 30299

EP - 30305

JO - ACS Omega

JF - ACS Omega

IS - 46

ER -

Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

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