Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions

Lihong Geng; Ali Naderi; Yimin Mao; Chengbo Zhan; Priyanka Sharma; Xiangfang Peng; Benjamin S. Hsiao

doi:10.1021/bk-2017-1251.ch006

Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions

Lihong Geng
, Ali Naderi
, Yimin Mao
, Chengbo Zhan
, Priyanka Sharma
, Xiangfang Peng
, Benjamin S. Hsiao

Chemistry

South China University of Technology
Stony Brook University
BillerudKorsnäs AB
University of Maryland, College Park
National Institute of Standards and Technology

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

19 Scopus citations

Abstract

Cellulose nanofibers (CNF) were produced by 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) oxidation and mechanical shearing of jute pulp. The cross section dimension of CNFs was determined by small-angle neuron scattering (SANS), yielding a width of about 5 nm and thickness of about 1.5 nm, which were further confirmed by transmission electron microscopy (TEM). The effect of NaCl concentration on the rheological properties of the jute-based CNF as a function of concentration was investigated. The viscosity of CNF suspensions was found to increase by addition of the monovalent NaCl, which exhibited a critical concentration behavior. However, the critical concentration value was highly dependent on the CNF concentration. The effect of the cation valency on the rheological properties was also investigated. It was found that both viscosity and stiffness of the CNF gel increased with increasing the valency of the cation.

Original language	English
Title of host publication	ACS Symposium Series
Editors	Umesh P. Agarwal, Rajai H. Atalla, Akira Isogai
Publisher	American Chemical Society
Pages	113-132
Number of pages	20
DOIs	https://doi.org/10.1021/bk-2017-1251.ch006
State	Published - 2017

Publication series

Name	ACS Symposium Series
Volume	1251
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

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10.1021/bk-2017-1251.ch006

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Geng, L., Naderi, A., Mao, Y., Zhan, C., Sharma, P., Peng, X., & Hsiao, B. S. (2017). Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions. In U. P. Agarwal, R. H. Atalla, & A. Isogai (Eds.), ACS Symposium Series (pp. 113-132). (ACS Symposium Series; Vol. 1251). American Chemical Society. https://doi.org/10.1021/bk-2017-1251.ch006

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title = "Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions",

abstract = "Cellulose nanofibers (CNF) were produced by 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) oxidation and mechanical shearing of jute pulp. The cross section dimension of CNFs was determined by small-angle neuron scattering (SANS), yielding a width of about 5 nm and thickness of about 1.5 nm, which were further confirmed by transmission electron microscopy (TEM). The effect of NaCl concentration on the rheological properties of the jute-based CNF as a function of concentration was investigated. The viscosity of CNF suspensions was found to increase by addition of the monovalent NaCl, which exhibited a critical concentration behavior. However, the critical concentration value was highly dependent on the CNF concentration. The effect of the cation valency on the rheological properties was also investigated. It was found that both viscosity and stiffness of the CNF gel increased with increasing the valency of the cation.",

author = "Lihong Geng and Ali Naderi and Yimin Mao and Chengbo Zhan and Priyanka Sharma and Xiangfang Peng and Hsiao, \{Benjamin S.\}",

year = "2017",

doi = "10.1021/bk-2017-1251.ch006",

language = "English",

series = "ACS Symposium Series",

publisher = "American Chemical Society",

pages = "113--132",

editor = "Agarwal, \{Umesh P.\} and Atalla, \{Rajai H.\} and Akira Isogai",

booktitle = "ACS Symposium Series",

}

Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions. / Geng, Lihong; Naderi, Ali; Mao, Yimin et al.
ACS Symposium Series. ed. / Umesh P. Agarwal; Rajai H. Atalla; Akira Isogai. American Chemical Society, 2017. p. 113-132 (ACS Symposium Series; Vol. 1251).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions

AU - Geng, Lihong

AU - Naderi, Ali

AU - Mao, Yimin

AU - Zhan, Chengbo

AU - Sharma, Priyanka

AU - Peng, Xiangfang

AU - Hsiao, Benjamin S.

PY - 2017

Y1 - 2017

N2 - Cellulose nanofibers (CNF) were produced by 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) oxidation and mechanical shearing of jute pulp. The cross section dimension of CNFs was determined by small-angle neuron scattering (SANS), yielding a width of about 5 nm and thickness of about 1.5 nm, which were further confirmed by transmission electron microscopy (TEM). The effect of NaCl concentration on the rheological properties of the jute-based CNF as a function of concentration was investigated. The viscosity of CNF suspensions was found to increase by addition of the monovalent NaCl, which exhibited a critical concentration behavior. However, the critical concentration value was highly dependent on the CNF concentration. The effect of the cation valency on the rheological properties was also investigated. It was found that both viscosity and stiffness of the CNF gel increased with increasing the valency of the cation.

AB - Cellulose nanofibers (CNF) were produced by 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) oxidation and mechanical shearing of jute pulp. The cross section dimension of CNFs was determined by small-angle neuron scattering (SANS), yielding a width of about 5 nm and thickness of about 1.5 nm, which were further confirmed by transmission electron microscopy (TEM). The effect of NaCl concentration on the rheological properties of the jute-based CNF as a function of concentration was investigated. The viscosity of CNF suspensions was found to increase by addition of the monovalent NaCl, which exhibited a critical concentration behavior. However, the critical concentration value was highly dependent on the CNF concentration. The effect of the cation valency on the rheological properties was also investigated. It was found that both viscosity and stiffness of the CNF gel increased with increasing the valency of the cation.

UR - https://www.scopus.com/pages/publications/85074795812

U2 - 10.1021/bk-2017-1251.ch006

DO - 10.1021/bk-2017-1251.ch006

M3 - Chapter

AN - SCOPUS:85074795812

T3 - ACS Symposium Series

SP - 113

EP - 132

BT - ACS Symposium Series

A2 - Agarwal, Umesh P.

A2 - Atalla, Rajai H.

A2 - Isogai, Akira

PB - American Chemical Society

ER -

Rheological Properties of Jute-Based Cellulose Nanofibers under Different Ionic Conditions

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