Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis

Karena W. Chapman; Peter J. Chupas; Cameron J. Kepert

doi:10.1021/ja053266k

Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis

Karena W. Chapman
, Peter J. Chupas
, Cameron J. Kepert

Chemistry

Argonne National Laboratory
The University of Sydney

Research output: Contribution to journal › Article › peer-review

106 Scopus citations

Abstract

We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N₂ molecules in the Prussian blue system Mn₃[Co(CN)₆]₂·x{N₂}. The differential PDF shows a distributed orientation of N₂ molecules constrained to sites centered about the (1/4,1/4,1/4) positions within the pores. The results show a subtle response of the framework to guest loading which corresponds principally to the perturbation of the Mn ion coordination.

Original language	English
Pages (from-to)	11232-11233
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	32
DOIs	https://doi.org/10.1021/ja053266k
State	Published - Aug 17 2005

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title = "Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis",

abstract = "We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N2 molecules in the Prussian blue system Mn3[Co(CN)6]2·x\{N2\}. The differential PDF shows a distributed orientation of N2 molecules constrained to sites centered about the (1/4,1/4,1/4) positions within the pores. The results show a subtle response of the framework to guest loading which corresponds principally to the perturbation of the Mn ion coordination.",

author = "Chapman, \{Karena W.\} and Chupas, \{Peter J.\} and Kepert, \{Cameron J.\}",

year = "2005",

month = aug,

day = "17",

doi = "10.1021/ja053266k",

language = "English",

volume = "127",

pages = "11232--11233",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

number = "32",

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Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis. / Chapman, Karena W.; Chupas, Peter J.; Kepert, Cameron J.
In: Journal of the American Chemical Society, Vol. 127, No. 32, 17.08.2005, p. 11232-11233.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction

T2 - A differential pair distribution function analysis

AU - Chapman, Karena W.

AU - Chupas, Peter J.

AU - Kepert, Cameron J.

PY - 2005/8/17

Y1 - 2005/8/17

N2 - We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N2 molecules in the Prussian blue system Mn3[Co(CN)6]2·x{N2}. The differential PDF shows a distributed orientation of N2 molecules constrained to sites centered about the (1/4,1/4,1/4) positions within the pores. The results show a subtle response of the framework to guest loading which corresponds principally to the perturbation of the Mn ion coordination.

AB - We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N2 molecules in the Prussian blue system Mn3[Co(CN)6]2·x{N2}. The differential PDF shows a distributed orientation of N2 molecules constrained to sites centered about the (1/4,1/4,1/4) positions within the pores. The results show a subtle response of the framework to guest loading which corresponds principally to the perturbation of the Mn ion coordination.

UR - https://www.scopus.com/pages/publications/23844533204

U2 - 10.1021/ja053266k

DO - 10.1021/ja053266k

M3 - Article

AN - SCOPUS:23844533204

SN - 0002-7863

VL - 127

SP - 11232

EP - 11233

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 32

ER -

Selective recovery of dynamic guest structure in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis

Abstract

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