Specific guest orientation in guest-host association with a transition metal complex containing a permanent void

Whei Lu Kwik; Norman Herron; Kenneth Takeuchi; Daryle Busch

doi:10.1039/C39830000409

Specific guest orientation in guest-host association with a transition metal complex containing a permanent void

Whei Lu Kwik
, Norman Herron
, Kenneth Takeuchi
, Daryle Busch

Chemistry

Ohio State University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

¹H N.m.r. longitudinal relaxation time measurements in aqueous solution are used to estimate distances from the protons of guest molecules to a paramagnetic copper(II) macrobicyclic complex whose ligand is known to facilitate O₂ binding to both Co^II and Fe^II while in addition being sufficiently spacious to accommodate a number of organic substrates for potential autoxidation.

Original language	English
Pages (from-to)	409-411
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39830000409
State	Published - 1983

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title = "Specific guest orientation in guest-host association with a transition metal complex containing a permanent void",

abstract = "1H N.m.r. longitudinal relaxation time measurements in aqueous solution are used to estimate distances from the protons of guest molecules to a paramagnetic copper(II) macrobicyclic complex whose ligand is known to facilitate O2 binding to both CoII and FeII while in addition being sufficiently spacious to accommodate a number of organic substrates for potential autoxidation.",

author = "Kwik, \{Whei Lu\} and Norman Herron and Kenneth Takeuchi and Daryle Busch",

year = "1983",

doi = "10.1039/C39830000409",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Specific guest orientation in guest-host association with a transition metal complex containing a permanent void

AU - Kwik, Whei Lu

AU - Herron, Norman

AU - Takeuchi, Kenneth

AU - Busch, Daryle

PY - 1983

Y1 - 1983

N2 - 1H N.m.r. longitudinal relaxation time measurements in aqueous solution are used to estimate distances from the protons of guest molecules to a paramagnetic copper(II) macrobicyclic complex whose ligand is known to facilitate O2 binding to both CoII and FeII while in addition being sufficiently spacious to accommodate a number of organic substrates for potential autoxidation.

AB - 1H N.m.r. longitudinal relaxation time measurements in aqueous solution are used to estimate distances from the protons of guest molecules to a paramagnetic copper(II) macrobicyclic complex whose ligand is known to facilitate O2 binding to both CoII and FeII while in addition being sufficiently spacious to accommodate a number of organic substrates for potential autoxidation.

UR - https://www.scopus.com/pages/publications/37049112586

U2 - 10.1039/C39830000409

DO - 10.1039/C39830000409

M3 - Article

AN - SCOPUS:37049112586

SN - 0022-4936

SP - 409

EP - 411

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Specific guest orientation in guest-host association with a transition metal complex containing a permanent void

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