Stereochemistry of the regiospecific hydrosilylation of isoprene catalyzed by a phosphine-palladium complex

Iwao Ojima

doi:10.1016/S0022-328X(00)93621-0

Stereochemistry of the regiospecific hydrosilylation of isoprene catalyzed by a phosphine-palladium complex

Iwao Ojima

Chemistry

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Abstract

Hydrosilylation of isoprene catalyzed by a palladium complex prepared in situ from triphenylphosphine and bis(benzonitrile)palladium dichloride was studied. The reaction was found to proceed regioselectively and stereoselectively to give (Z)-2-methylbuten-2-ylsilane exclusively. The stereochemistry of the 2-methylbuten-2-ylsilane was elucidated on the basis of NMR Spectroscopy, measuring the nuclear Overhauser effect. A possible mechanism of the reaction is proposed.

Original language	English
Pages (from-to)	C1-C5
Journal	Journal of Organometallic Chemistry
Volume	134
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)93621-0
State	Published - Jul 5 1977

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title = "Stereochemistry of the regiospecific hydrosilylation of isoprene catalyzed by a phosphine-palladium complex",

abstract = "Hydrosilylation of isoprene catalyzed by a palladium complex prepared in situ from triphenylphosphine and bis(benzonitrile)palladium dichloride was studied. The reaction was found to proceed regioselectively and stereoselectively to give (Z)-2-methylbuten-2-ylsilane exclusively. The stereochemistry of the 2-methylbuten-2-ylsilane was elucidated on the basis of NMR Spectroscopy, measuring the nuclear Overhauser effect. A possible mechanism of the reaction is proposed.",

author = "Iwao Ojima",

year = "1977",

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AU - Ojima, Iwao

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N2 - Hydrosilylation of isoprene catalyzed by a palladium complex prepared in situ from triphenylphosphine and bis(benzonitrile)palladium dichloride was studied. The reaction was found to proceed regioselectively and stereoselectively to give (Z)-2-methylbuten-2-ylsilane exclusively. The stereochemistry of the 2-methylbuten-2-ylsilane was elucidated on the basis of NMR Spectroscopy, measuring the nuclear Overhauser effect. A possible mechanism of the reaction is proposed.

AB - Hydrosilylation of isoprene catalyzed by a palladium complex prepared in situ from triphenylphosphine and bis(benzonitrile)palladium dichloride was studied. The reaction was found to proceed regioselectively and stereoselectively to give (Z)-2-methylbuten-2-ylsilane exclusively. The stereochemistry of the 2-methylbuten-2-ylsilane was elucidated on the basis of NMR Spectroscopy, measuring the nuclear Overhauser effect. A possible mechanism of the reaction is proposed.

UR - https://www.scopus.com/pages/publications/4244042267

U2 - 10.1016/S0022-328X(00)93621-0

DO - 10.1016/S0022-328X(00)93621-0

M3 - Article

AN - SCOPUS:4244042267

SN - 0022-328X

VL - 134

SP - C1-C5

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Stereochemistry of the regiospecific hydrosilylation of isoprene catalyzed by a phosphine-palladium complex

Abstract

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