Synthesis and structure characterization of copper terephthalate metal-organic frameworks

Cantwell G. Carson; Kenneth Hardcastle; Justin Schwartz; Xiaotao Liu; Christina Hoffmann; Rosario A. Gerhardt; Rina Tannenbaum

doi:10.1002/ejic.200801224

Synthesis and structure characterization of copper terephthalate metal-organic frameworks

Cantwell G. Carson
, Kenneth Hardcastle
, Justin Schwartz
, Xiaotao Liu
, Christina Hoffmann
, Rosario A. Gerhardt
, Rina Tannenbaum

Materials Science and Engineering

Georgia Institute of Technology
Emory University
Florida State University
FAMU–FSU College of Engineering
Spallation Neutron Source

Research output: Contribution to journal › Article › peer-review

381 Scopus citations

Abstract

In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.

Original language	English
Pages (from-to)	2338-2343
Number of pages	6
Journal	Chemische Berichte
Issue number	16
DOIs	https://doi.org/10.1002/ejic.200801224
State	Published - Jun 2009

Keywords

Carboxylate ligands
Coordination polymers
Crystal engineering
Magnetic properties
Metal-organic frameworks
Microporous materials

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10.1002/ejic.200801224

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title = "Synthesis and structure characterization of copper terephthalate metal-organic frameworks",

abstract = "In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.",

keywords = "Carboxylate ligands, Coordination polymers, Crystal engineering, Magnetic properties, Metal-organic frameworks, Microporous materials",

author = "Carson, \{Cantwell G.\} and Kenneth Hardcastle and Justin Schwartz and Xiaotao Liu and Christina Hoffmann and Gerhardt, \{Rosario A.\} and Rina Tannenbaum",

year = "2009",

month = jun,

doi = "10.1002/ejic.200801224",

language = "English",

pages = "2338--2343",

journal = "Chemische Berichte",

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T1 - Synthesis and structure characterization of copper terephthalate metal-organic frameworks

AU - Carson, Cantwell G.

AU - Hardcastle, Kenneth

AU - Schwartz, Justin

AU - Liu, Xiaotao

AU - Hoffmann, Christina

AU - Gerhardt, Rosario A.

AU - Tannenbaum, Rina

PY - 2009/6

Y1 - 2009/6

N2 - In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.

AB - In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.

KW - Carboxylate ligands

KW - Coordination polymers

KW - Crystal engineering

KW - Magnetic properties

KW - Metal-organic frameworks

KW - Microporous materials

UR - https://www.scopus.com/pages/publications/66149154608

U2 - 10.1002/ejic.200801224

DO - 10.1002/ejic.200801224

M3 - Article

AN - SCOPUS:66149154608

SN - 0009-2940

SP - 2338

EP - 2343

JO - Chemische Berichte

JF - Chemische Berichte

IS - 16

ER -

Synthesis and structure characterization of copper terephthalate metal-organic frameworks

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Keywords

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