Synthesis of a novel two-dimensional antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, and its structure solution using synchrotron/imaging plate data

Younghee Ko; Kemin Tan; John B. Parise; Alex Darovsky

doi:10.1021/cm950402j

Synthesis of a novel two-dimensional antimony sulfide, [C₄H₁₀N]₂[Sb₈S ₁₃]·0.15H₂O, and its structure solution using synchrotron/imaging plate data

Younghee Ko
, Kemin Tan
, John B. Parise
, Alex Darovsky

Geosciences

Stony Brook University
Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

A novel antimony sulfide, [C₄H₁₀N]₂[Sb₈S ₁₃]·0.15H₂O, was synthesized hydrothermally, and its structure was determined from data collected using a synchrotron/imaging plate system. The new compound consists of centrosymmetric Sb₁₆S₂₆^4- planar clusters. Each cluster is connected to four others through two edge-sharing and two corner-sharing SbS₃ pyramids, forming an extended sheet. The protonated pyrrolidine molecules reside between the parallel stacked sheets. The structure is triclinic (space group P1) with α = 6.929(2) Å, b = 16.747(2) Å, c = 17.976(4) Å, α = 94.84(1°), β = 95.41(1)°, and γ = 125.28(1)°.

Original language	English
Pages (from-to)	493-496
Number of pages	4
Journal	Chemistry of Materials
Volume	8
Issue number	2
DOIs	https://doi.org/10.1021/cm950402j
State	Published - Feb 1996

Access to Document

10.1021/cm950402j

Cite this

@article{0df92de8fccf4b37af741b5a7d7deb12,

title = "Synthesis of a novel two-dimensional antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, and its structure solution using synchrotron/imaging plate data",

abstract = "A novel antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, was synthesized hydrothermally, and its structure was determined from data collected using a synchrotron/imaging plate system. The new compound consists of centrosymmetric Sb16S264- planar clusters. Each cluster is connected to four others through two edge-sharing and two corner-sharing SbS3 pyramids, forming an extended sheet. The protonated pyrrolidine molecules reside between the parallel stacked sheets. The structure is triclinic (space group P1) with α = 6.929(2) {\AA}, b = 16.747(2) {\AA}, c = 17.976(4) {\AA}, α = 94.84(1°), β = 95.41(1)°, and γ = 125.28(1)°.",

author = "Younghee Ko and Kemin Tan and Parise, \{John B.\} and Alex Darovsky",

year = "1996",

month = feb,

doi = "10.1021/cm950402j",

language = "English",

volume = "8",

pages = "493--496",

journal = "Chemistry of Materials",

issn = "0897-4756",

number = "2",

}

TY - JOUR

T1 - Synthesis of a novel two-dimensional antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, and its structure solution using synchrotron/imaging plate data

AU - Ko, Younghee

AU - Tan, Kemin

AU - Parise, John B.

AU - Darovsky, Alex

PY - 1996/2

Y1 - 1996/2

N2 - A novel antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, was synthesized hydrothermally, and its structure was determined from data collected using a synchrotron/imaging plate system. The new compound consists of centrosymmetric Sb16S264- planar clusters. Each cluster is connected to four others through two edge-sharing and two corner-sharing SbS3 pyramids, forming an extended sheet. The protonated pyrrolidine molecules reside between the parallel stacked sheets. The structure is triclinic (space group P1) with α = 6.929(2) Å, b = 16.747(2) Å, c = 17.976(4) Å, α = 94.84(1°), β = 95.41(1)°, and γ = 125.28(1)°.

AB - A novel antimony sulfide, [C4H10N]2[Sb8S 13]·0.15H2O, was synthesized hydrothermally, and its structure was determined from data collected using a synchrotron/imaging plate system. The new compound consists of centrosymmetric Sb16S264- planar clusters. Each cluster is connected to four others through two edge-sharing and two corner-sharing SbS3 pyramids, forming an extended sheet. The protonated pyrrolidine molecules reside between the parallel stacked sheets. The structure is triclinic (space group P1) with α = 6.929(2) Å, b = 16.747(2) Å, c = 17.976(4) Å, α = 94.84(1°), β = 95.41(1)°, and γ = 125.28(1)°.

UR - https://www.scopus.com/pages/publications/0000421815

U2 - 10.1021/cm950402j

DO - 10.1021/cm950402j

M3 - Article

AN - SCOPUS:0000421815

SN - 0897-4756

VL - 8

SP - 493

EP - 496

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 2

ER -

Synthesis of a novel two-dimensional antimony sulfide, [C₄H₁₀N]₂[Sb₈S ₁₃]·0.15H₂O, and its structure solution using synchrotron/imaging plate data

Abstract

Access to Document

Other files and links

Fingerprint

Cite this