Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

Natalie St. Fleur; J. Craig Hili; Andreas Mayr

doi:10.1016/j.ica.2008.07.031

Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

Natalie St. Fleur
, J. Craig Hili
, Andreas Mayr

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N′-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides.

Original language	English
Pages (from-to)	1571-1576
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	362
Issue number	5
DOIs	https://doi.org/10.1016/j.ica.2008.07.031
State	Published - Apr 1 2009

Keywords

Alkynylrhenium complex
Bis(isocyanide)rhenium complex
Diamine rhenium complex
Phenanthroline rhenium complex

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10.1016/j.ica.2008.07.031

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title = "Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand",

abstract = "Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N′-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides.",

keywords = "Alkynylrhenium complex, Bis(isocyanide)rhenium complex, Diamine rhenium complex, Phenanthroline rhenium complex",

author = "\{St. Fleur\}, Natalie and \{Craig Hili\}, J. and Andreas Mayr",

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journal = "Inorganica Chimica Acta",

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T1 - Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

AU - St. Fleur, Natalie

AU - Craig Hili, J.

AU - Mayr, Andreas

PY - 2009/4/1

Y1 - 2009/4/1

N2 - Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N′-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides.

AB - Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N′-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides.

KW - Alkynylrhenium complex

KW - Bis(isocyanide)rhenium complex

KW - Diamine rhenium complex

KW - Phenanthroline rhenium complex

UR - https://www.scopus.com/pages/publications/60849092236

U2 - 10.1016/j.ica.2008.07.031

DO - 10.1016/j.ica.2008.07.031

M3 - Article

AN - SCOPUS:60849092236

SN - 0020-1693

VL - 362

SP - 1571

EP - 1576

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 5

ER -

Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

Abstract

Keywords

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