Abstract
A selective sequence: An enantioselective synthesis (see scheme) of atropisomerically defined p-terphenyls, as well as tetra- and pentaaryl compounds is reported. The synthesis proceeds through sequential atropisomer-selective electrophilic aromatic substitution and regioselective palladium-catalyzed cross-coupling reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 5125-5129 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 22 |
| DOIs | |
| State | Published - May 23 2011 |
Keywords
- atropisomerism
- bromination
- cross-coupling reactions
- peptides
- regioselectivity
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