Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands

Andreas Mayr; Gregory A. McDermott; Alison M. Dorries

doi:10.1021/om00122a035

Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands

Andreas Mayr
, Gregory A. McDermott
, Alison M. Dorries

Chemistry

Princeton University

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Stable carbyne complexes of the type trans-X(CO)₂L₂M≡CR (M = Cr, Mo, W; R = C₆H₅, CH₃; X = Cl, Br, CF₃C(O)O, L₂ = 2 pyridine, tetramethylethylenediamine) are prepared in a single synthesis step by reaction of the respective acyl complexes [NMe₄] [(CO)₅MC(O)R] at low temperatures with COCl₂, C₂O₂Cl₂, CIC(O)OCCl₃, C₂O₂Br₂, or (CF₃CO)₂O and subsequent addition of the nitrogenous ligands at warmer temperatures.

Original language	English
Pages (from-to)	608-610
Number of pages	3
Journal	Organometallics
Volume	4
Issue number	3
DOIs	https://doi.org/10.1021/om00122a035
State	Published - 1985

Access to Document

10.1021/om00122a035

Cite this

@article{61259a694a39475780bc8278bc09f5e2,

title = "Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands",

abstract = "Stable carbyne complexes of the type trans-X(CO)2L2M≡CR (M = Cr, Mo, W; R = C6H5, CH3; X = Cl, Br, CF3C(O)O, L2 = 2 pyridine, tetramethylethylenediamine) are prepared in a single synthesis step by reaction of the respective acyl complexes [NMe4] [(CO)5MC(O)R] at low temperatures with COCl2, C2O2Cl2, CIC(O)OCCl3, C2O2Br2, or (CF3CO)2O and subsequent addition of the nitrogenous ligands at warmer temperatures.",

author = "Andreas Mayr and McDermott, \{Gregory A.\} and Dorries, \{Alison M.\}",

year = "1985",

doi = "10.1021/om00122a035",

language = "English",

volume = "4",

pages = "608--610",

journal = "Organometallics",

issn = "0276-7333",

number = "3",

}

TY - JOUR

T1 - Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands

AU - Mayr, Andreas

AU - McDermott, Gregory A.

AU - Dorries, Alison M.

PY - 1985

Y1 - 1985

N2 - Stable carbyne complexes of the type trans-X(CO)2L2M≡CR (M = Cr, Mo, W; R = C6H5, CH3; X = Cl, Br, CF3C(O)O, L2 = 2 pyridine, tetramethylethylenediamine) are prepared in a single synthesis step by reaction of the respective acyl complexes [NMe4] [(CO)5MC(O)R] at low temperatures with COCl2, C2O2Cl2, CIC(O)OCCl3, C2O2Br2, or (CF3CO)2O and subsequent addition of the nitrogenous ligands at warmer temperatures.

AB - Stable carbyne complexes of the type trans-X(CO)2L2M≡CR (M = Cr, Mo, W; R = C6H5, CH3; X = Cl, Br, CF3C(O)O, L2 = 2 pyridine, tetramethylethylenediamine) are prepared in a single synthesis step by reaction of the respective acyl complexes [NMe4] [(CO)5MC(O)R] at low temperatures with COCl2, C2O2Cl2, CIC(O)OCCl3, C2O2Br2, or (CF3CO)2O and subsequent addition of the nitrogenous ligands at warmer temperatures.

UR - https://www.scopus.com/pages/publications/0000442844

U2 - 10.1021/om00122a035

DO - 10.1021/om00122a035

M3 - Article

AN - SCOPUS:0000442844

SN - 0276-7333

VL - 4

SP - 608

EP - 610

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands

Abstract

Access to Document

Other files and links

Fingerprint

Cite this