Synthesis of Copolymers by Alternating ROMP (AROMP)

Airong Song; Kathlyn A. Parker; Nicole S. Sampson

doi:10.1021/ja809661k

Synthesis of Copolymers by Alternating ROMP (AROMP)

Airong Song
, Kathlyn A. Parker
, Nicole S. Sampson

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

106 Scopus citations

Abstract

The alternating polymerization of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H ₂IMes)(3-Br-pyr) ₂Cl ₂Ru CHPh] is described. This reaction is synthetically accessible and provides (AB)n heteropolymers with an alternating backbone and alternating functionality. The regiocontrol of heteropolymer formation derives from the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in combination with the favorable kinetics of cross polymerization.

Original language	English
Pages (from-to)	3444-3445
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	10
DOIs	https://doi.org/10.1021/ja809661k
State	Published - Mar 18 2009

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title = "Synthesis of Copolymers by Alternating ROMP (AROMP)",

abstract = "The alternating polymerization of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H 2IMes)(3-Br-pyr) 2Cl 2Ru CHPh] is described. This reaction is synthetically accessible and provides (AB)n heteropolymers with an alternating backbone and alternating functionality. The regiocontrol of heteropolymer formation derives from the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in combination with the favorable kinetics of cross polymerization.",

author = "Airong Song and Parker, \{Kathlyn A.\} and Sampson, \{Nicole S.\}",

year = "2009",

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journal = "Journal of the American Chemical Society",

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T1 - Synthesis of Copolymers by Alternating ROMP (AROMP)

AU - Song, Airong

AU - Parker, Kathlyn A.

AU - Sampson, Nicole S.

PY - 2009/3/18

Y1 - 2009/3/18

N2 - The alternating polymerization of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H 2IMes)(3-Br-pyr) 2Cl 2Ru CHPh] is described. This reaction is synthetically accessible and provides (AB)n heteropolymers with an alternating backbone and alternating functionality. The regiocontrol of heteropolymer formation derives from the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in combination with the favorable kinetics of cross polymerization.

AB - The alternating polymerization of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H 2IMes)(3-Br-pyr) 2Cl 2Ru CHPh] is described. This reaction is synthetically accessible and provides (AB)n heteropolymers with an alternating backbone and alternating functionality. The regiocontrol of heteropolymer formation derives from the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in combination with the favorable kinetics of cross polymerization.

UR - https://www.scopus.com/pages/publications/68049105974

U2 - 10.1021/ja809661k

DO - 10.1021/ja809661k

M3 - Article

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AN - SCOPUS:68049105974

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SP - 3444

EP - 3445

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 10

ER -

Synthesis of Copolymers by Alternating ROMP (AROMP)

Abstract

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