The carbonylation of RuCl3·3H2O in ethanol: an infrared spectroscopic study

Rina Tannenbaum

doi:10.1016/S0020-1693(00)85928-9

The carbonylation of RuCl₃·3H₂O in ethanol: an infrared spectroscopic study

Rina Tannenbaum

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The carbonylation of a RuCl₃·3H₂O solution in refluxing ethanol was monitored by means of infrared spectroscopy. The spectroscopic characteristics of the various intermediates were identified. Various concentrations of RuCl₃·3H₂O and various rates of CO bubbling were used to determine the dependence of the intermediates upon these parameters. Three main species were postulated to be present in solution during the carbonylation reaction.

Original language	English
Pages (from-to)	49-53
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	130
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)85928-9
State	Published - Jun 22 1987

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title = "The carbonylation of RuCl3·3H2O in ethanol: an infrared spectroscopic study",

abstract = "The carbonylation of a RuCl3·3H2O solution in refluxing ethanol was monitored by means of infrared spectroscopy. The spectroscopic characteristics of the various intermediates were identified. Various concentrations of RuCl3·3H2O and various rates of CO bubbling were used to determine the dependence of the intermediates upon these parameters. Three main species were postulated to be present in solution during the carbonylation reaction.",

author = "Rina Tannenbaum",

year = "1987",

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T1 - The carbonylation of RuCl3·3H2O in ethanol

T2 - an infrared spectroscopic study

AU - Tannenbaum, Rina

PY - 1987/6/22

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N2 - The carbonylation of a RuCl3·3H2O solution in refluxing ethanol was monitored by means of infrared spectroscopy. The spectroscopic characteristics of the various intermediates were identified. Various concentrations of RuCl3·3H2O and various rates of CO bubbling were used to determine the dependence of the intermediates upon these parameters. Three main species were postulated to be present in solution during the carbonylation reaction.

AB - The carbonylation of a RuCl3·3H2O solution in refluxing ethanol was monitored by means of infrared spectroscopy. The spectroscopic characteristics of the various intermediates were identified. Various concentrations of RuCl3·3H2O and various rates of CO bubbling were used to determine the dependence of the intermediates upon these parameters. Three main species were postulated to be present in solution during the carbonylation reaction.

UR - https://www.scopus.com/pages/publications/4243958370

U2 - 10.1016/S0020-1693(00)85928-9

DO - 10.1016/S0020-1693(00)85928-9

M3 - Article

AN - SCOPUS:4243958370

SN - 0020-1693

VL - 130

SP - 49

EP - 53

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

The carbonylation of RuCl₃·3H₂O in ethanol: an infrared spectroscopic study

Abstract

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