The dynamic structure of model catalyst surfaces under ambient conditions

A. Baber; J. A. Boscoboinik; K. Mudiyanselage; D. Stacchiola

doi:10.1016/B978-0-12-409547-2.13746-1

The dynamic structure of model catalyst surfaces under ambient conditions

A. Baber
, J. A. Boscoboinik
, K. Mudiyanselage
, D. Stacchiola

Materials Science and Engineering

James Madison University
SABIC
Brookhaven National Laboratory

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

In this chapter we present case studies showing how complementary in situ techniques including ambient pressure scanning tunneling microscopy, ambient pressure infrared reflection absorption spectroscopy, and ambient pressure X-ray photoelectron spectroscopy (AP-XPS) can be applied to study the dynamic oxide/metal interfaces formed on model heterogeneous catalyst surfaces. This approach helps to identify active local phases or structures on catalysts and critical adsorbate species during reaction conditions, thus guiding the determination of reaction mechanisms.

Original language	English
Title of host publication	Encyclopedia of Interfacial Chemistry
Subtitle of host publication	Surface Science and Electrochemistry
Publisher	Elsevier
Pages	658-675
Number of pages	18
ISBN (Electronic)	9780128098943
ISBN (Print)	9780128097397
DOIs	https://doi.org/10.1016/B978-0-12-409547-2.13746-1
State	Published - Jan 1 2018

Keywords

Ambient pressure
AP-IRRAS
AP-STM
AP-XPS
CO oxidation
Copper
In situ
Interface
Methanol synthesis
Mixed metal oxide
Nanoporous film
Thin film oxide
Water-gas shift reaction
Zeolite

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10.1016/B978-0-12-409547-2.13746-1

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title = "The dynamic structure of model catalyst surfaces under ambient conditions",

abstract = "In this chapter we present case studies showing how complementary in situ techniques including ambient pressure scanning tunneling microscopy, ambient pressure infrared reflection absorption spectroscopy, and ambient pressure X-ray photoelectron spectroscopy (AP-XPS) can be applied to study the dynamic oxide/metal interfaces formed on model heterogeneous catalyst surfaces. This approach helps to identify active local phases or structures on catalysts and critical adsorbate species during reaction conditions, thus guiding the determination of reaction mechanisms.",

keywords = "Ambient pressure, AP-IRRAS, AP-STM, AP-XPS, CO oxidation, Copper, In situ, Interface, Methanol synthesis, Mixed metal oxide, Nanoporous film, Thin film oxide, Water-gas shift reaction, Zeolite",

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doi = "10.1016/B978-0-12-409547-2.13746-1",

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T1 - The dynamic structure of model catalyst surfaces under ambient conditions

AU - Baber, A.

AU - Boscoboinik, J. A.

AU - Mudiyanselage, K.

AU - Stacchiola, D.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - In this chapter we present case studies showing how complementary in situ techniques including ambient pressure scanning tunneling microscopy, ambient pressure infrared reflection absorption spectroscopy, and ambient pressure X-ray photoelectron spectroscopy (AP-XPS) can be applied to study the dynamic oxide/metal interfaces formed on model heterogeneous catalyst surfaces. This approach helps to identify active local phases or structures on catalysts and critical adsorbate species during reaction conditions, thus guiding the determination of reaction mechanisms.

AB - In this chapter we present case studies showing how complementary in situ techniques including ambient pressure scanning tunneling microscopy, ambient pressure infrared reflection absorption spectroscopy, and ambient pressure X-ray photoelectron spectroscopy (AP-XPS) can be applied to study the dynamic oxide/metal interfaces formed on model heterogeneous catalyst surfaces. This approach helps to identify active local phases or structures on catalysts and critical adsorbate species during reaction conditions, thus guiding the determination of reaction mechanisms.

KW - Ambient pressure

KW - AP-IRRAS

KW - AP-STM

KW - AP-XPS

KW - CO oxidation

KW - Copper

KW - In situ

KW - Interface

KW - Methanol synthesis

KW - Mixed metal oxide

KW - Nanoporous film

KW - Thin film oxide

KW - Water-gas shift reaction

KW - Zeolite

UR - https://www.scopus.com/pages/publications/85079256207

U2 - 10.1016/B978-0-12-409547-2.13746-1

DO - 10.1016/B978-0-12-409547-2.13746-1

M3 - Chapter

AN - SCOPUS:85079256207

SN - 9780128097397

SP - 658

EP - 675

BT - Encyclopedia of Interfacial Chemistry

PB - Elsevier

ER -

The dynamic structure of model catalyst surfaces under ambient conditions

Abstract

Keywords

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