Abstract
We computationally investigate the decay of surface effects in one-, two-, and three-dimensional materials using two-band tight-binding models. These general models facilitate a direct comparison between materials of differing dimensionality, which reveals that material dimensionality (not material-specific chemistry/physics) is the primary factor controlling the decay of surface effects. Our results corroborate more sophisticated, material-specific studies, finding that surface effects decay after ∼10, ∼25, and 100 layers in three-dimensional, two-dimensional, and one-dimensional materials, respectively. Physically, higher-dimensional materials screen surface effects more efficiently, as theoretically described by integration over each layer's Brillouin zone. Finally, we discuss several implications of these results.
| Original language | English |
|---|---|
| Article number | 084707 |
| Journal | Journal of Chemical Physics |
| Volume | 138 |
| Issue number | 8 |
| DOIs | |
| State | Published - Feb 28 2013 |
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