The Role of Organosilicon Compounds in Selective Organic Synthesis

Iwao Ojima; Takamasa Fuchikami

doi:10.5059/yukigoseikyokaishi.37.739

The Role of Organosilicon Compounds in Selective Organic Synthesis

Iwao Ojima
, Takamasa Fuchikami

Chemistry

Sagami Chemical Research Institute

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

This review article deals with some latest aspects of organosilicon compounds which were in used selective organic synthesis. Application of the electrophilic substitution of organosilicon compounds such as alkenylsilane, alkynylsilane and allylsilane is described with some emphasis. Organic Synthesis using Diels-Alder cycloaddition of silicon enolates is also included. The role of the silicon-carbon bond in these highly selective reactions will be disclosed.

Original language	English
Pages (from-to)	739-754
Number of pages	16
Journal	Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume	37
Issue number	9
DOIs	https://doi.org/10.5059/yukigoseikyokaishi.37.739
State	Published - 1979

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abstract = "This review article deals with some latest aspects of organosilicon compounds which were in used selective organic synthesis. Application of the electrophilic substitution of organosilicon compounds such as alkenylsilane, alkynylsilane and allylsilane is described with some emphasis. Organic Synthesis using Diels-Alder cycloaddition of silicon enolates is also included. The role of the silicon-carbon bond in these highly selective reactions will be disclosed.",

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AB - This review article deals with some latest aspects of organosilicon compounds which were in used selective organic synthesis. Application of the electrophilic substitution of organosilicon compounds such as alkenylsilane, alkynylsilane and allylsilane is described with some emphasis. Organic Synthesis using Diels-Alder cycloaddition of silicon enolates is also included. The role of the silicon-carbon bond in these highly selective reactions will be disclosed.

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The Role of Organosilicon Compounds in Selective Organic Synthesis

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