The stereochemistry of the addition of hydrosilanes to alkyl acetylenes catalyzed by tris(triphenylphosphine)-chlororhodium

Iwao Ojima; Miyoko Kumagai; Yoichiro Nagai

doi:10.1016/S0022-328X(00)93873-7

The stereochemistry of the addition of hydrosilanes to alkyl acetylenes catalyzed by tris(triphenylphosphine)-chlororhodium

Iwao Ojima
, Miyoko Kumagai
, Yoichiro Nagai

Chemistry

Sagami Chemical Research Institute
Gunma University

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

Tris(triphenylphosphine)chlororhodium was found to be an effective catalyst for the hydrosilylation of acetylenes. An unusual stereochemistry of addition was observed in the reaction of alkylacetylenes with hydrosilanes; the rhodium-catalyzed reaction involves a stereoselective trans addition.

Original language	English
Pages (from-to)	C14-C16
Journal	Journal of Organometallic Chemistry
Volume	66
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)93873-7
State	Published - Feb 14 1974

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title = "The stereochemistry of the addition of hydrosilanes to alkyl acetylenes catalyzed by tris(triphenylphosphine)-chlororhodium",

abstract = "Tris(triphenylphosphine)chlororhodium was found to be an effective catalyst for the hydrosilylation of acetylenes. An unusual stereochemistry of addition was observed in the reaction of alkylacetylenes with hydrosilanes; the rhodium-catalyzed reaction involves a stereoselective trans addition.",

author = "Iwao Ojima and Miyoko Kumagai and Yoichiro Nagai",

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AU - Ojima, Iwao

AU - Kumagai, Miyoko

AU - Nagai, Yoichiro

PY - 1974/2/14

Y1 - 1974/2/14

N2 - Tris(triphenylphosphine)chlororhodium was found to be an effective catalyst for the hydrosilylation of acetylenes. An unusual stereochemistry of addition was observed in the reaction of alkylacetylenes with hydrosilanes; the rhodium-catalyzed reaction involves a stereoselective trans addition.

AB - Tris(triphenylphosphine)chlororhodium was found to be an effective catalyst for the hydrosilylation of acetylenes. An unusual stereochemistry of addition was observed in the reaction of alkylacetylenes with hydrosilanes; the rhodium-catalyzed reaction involves a stereoselective trans addition.

UR - https://www.scopus.com/pages/publications/0007886738

U2 - 10.1016/S0022-328X(00)93873-7

DO - 10.1016/S0022-328X(00)93873-7

M3 - Article

AN - SCOPUS:0007886738

SN - 0022-328X

VL - 66

SP - C14-C16

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The stereochemistry of the addition of hydrosilanes to alkyl acetylenes catalyzed by tris(triphenylphosphine)-chlororhodium

Abstract

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