Abstract
It is the main purpose of this work to examine the polymerization process of Ru(II) with 1,4-diisocyanobenzene, the physical and spectral properties of the polymers formed and their potential catalytic activity. Special attention is devoted to the existance or absence of the metal-metal stacking interactions and its implication on the overall geometry of the new coordination polymers. The results of a preliminary study of the catalytic properties of the polymer in the hydrogenation reaction of 1-hexene are shown. The polymer seems to be an efficient but a non-selective catalyst with a turn-over ratio of 1:100.
| Original language | English |
|---|---|
| Pages (from-to) | 714-715 |
| Number of pages | 2 |
| Journal | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Volume | 31 |
| Issue number | 1 |
| State | Published - Apr 1990 |
| Event | Papers Presented at the Boston, Massachusetts Meeting of ACS 1989 - Boston, MA, USA Duration: Apr 22 1989 → Apr 27 1989 |
Fingerprint
Dive into the research topics of 'Three-dimensional coordination polymers of Ru(II) with diisocyanobenzene ligands and their catalytic activity'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver