Transition-metal complexes containing trans-spanning diphosphine ligands

Carol A. Bessel; Pooja Aggarwal; Amy C. Marschilok; Kenneth J. Takeuchi

doi:10.1021/cr990346w

Transition-metal complexes containing trans-spanning diphosphine ligands

Carol A. Bessel
, Pooja Aggarwal
, Amy C. Marschilok
, Kenneth J. Takeuchi

Chemistry

Villanova University

Research output: Contribution to journal › Review article › peer-review

143 Scopus citations

Abstract

The transition metal complexes containing trans-spanning diphosphine ligands were analyzed. The ligand positions in trans-spanning tertiary phosphine ligands can be sterically crowded or sheltered and the trans-spanning linkages can be modified. To fully realize the reactive potential of transition-metal complexes that contain trans-spanning tertiary phosphine ligands, it is necessary to develop ligands where isomerization is reduced.

Original language	English
Pages (from-to)	1031-1066
Number of pages	36
Journal	Chemical Reviews
Volume	101
Issue number	4
DOIs	https://doi.org/10.1021/cr990346w
State	Published - Apr 2001

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title = "Transition-metal complexes containing trans-spanning diphosphine ligands",

abstract = "The transition metal complexes containing trans-spanning diphosphine ligands were analyzed. The ligand positions in trans-spanning tertiary phosphine ligands can be sterically crowded or sheltered and the trans-spanning linkages can be modified. To fully realize the reactive potential of transition-metal complexes that contain trans-spanning tertiary phosphine ligands, it is necessary to develop ligands where isomerization is reduced.",

author = "Bessel, \{Carol A.\} and Pooja Aggarwal and Marschilok, \{Amy C.\} and Takeuchi, \{Kenneth J.\}",

year = "2001",

month = apr,

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language = "English",

volume = "101",

pages = "1031--1066",

journal = "Chemical Reviews",

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T1 - Transition-metal complexes containing trans-spanning diphosphine ligands

AU - Bessel, Carol A.

AU - Aggarwal, Pooja

AU - Marschilok, Amy C.

AU - Takeuchi, Kenneth J.

PY - 2001/4

Y1 - 2001/4

N2 - The transition metal complexes containing trans-spanning diphosphine ligands were analyzed. The ligand positions in trans-spanning tertiary phosphine ligands can be sterically crowded or sheltered and the trans-spanning linkages can be modified. To fully realize the reactive potential of transition-metal complexes that contain trans-spanning tertiary phosphine ligands, it is necessary to develop ligands where isomerization is reduced.

AB - The transition metal complexes containing trans-spanning diphosphine ligands were analyzed. The ligand positions in trans-spanning tertiary phosphine ligands can be sterically crowded or sheltered and the trans-spanning linkages can be modified. To fully realize the reactive potential of transition-metal complexes that contain trans-spanning tertiary phosphine ligands, it is necessary to develop ligands where isomerization is reduced.

UR - https://www.scopus.com/pages/publications/0035323797

U2 - 10.1021/cr990346w

DO - 10.1021/cr990346w

M3 - Review article

AN - SCOPUS:0035323797

SN - 0009-2665

VL - 101

SP - 1031

EP - 1066

JO - Chemical Reviews

JF - Chemical Reviews

IS - 4

ER -

Transition-metal complexes containing trans-spanning diphosphine ligands

Abstract

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