Transition metal complexes of cyanoisocyanoarenes as building blocks for one-, two-, and three-dimensional molecular solids

Li Feng Mao; Andreas Mayr

doi:10.1021/ic950580e

Transition metal complexes of cyanoisocyanoarenes as building blocks for one-, two-, and three-dimensional molecular solids

Li Feng Mao
, Andreas Mayr

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The complexes trans-[MI₂(CNC₆H₄-CN-4)₂]< (M = Pd and Ft), trans-[FeI₂L₄] (L = CNC₆H₄-CN-4 and CNC₆H₂-Me_2-2.6-CN-4), and [Mn(CNC₆H₄-CN-4)₆][SO₃CF ₃] were prepared. The compounds are thermally stable up to 230 °C or higher. The molecular structure of trans-[FeI₂(CNC₆H₄-CN-4)₄] was determined by X-ray crystallography: monoclinic, space group P2₁/n, a = 11.570(2) Å, b = 10.1052(8) Å, c = 28.138(7) Å, β= 92.034(9)°, Z = 4, 3464 unique reflections, R = 0.074, R_w = 0.089. The complexes contain the peripheral cyano groups in linear, planar, and octahedral dispositions, respectively. Solids were obtained by combining solutions of [PdI₂(CNC₆H₄-CN-4)₂] and [Cu(hfacac)₂], [FeI₂CNC₆H₄-CN-4₄)] and AgSO₃CF₃, [FeI₂(CNC₆H₂-Me₂-2,6-CN-4) ₄] and [Rh₂(O₂CCF₃)₄], and [Mn(CNC₆H₄-CN-4)₆][SO₃CF ₃] and [Rh₂(O₂CCF₃)₄]. [PdI₂(CNC₆H₄-CN-4)₂] and [Cu(hfacac)₂] in a ratio of 1:2 form a crystalline, one-dimensional solid: monoclinic, space group P2₁/c, a = 8.317(2) Å, b = 13.541(1) Å, c = 22.568(5) Å β= 100.45(1)°, Z = 2, 3279 unique reflections, R = 0.037, R_w = 0.047.

Original language	English
Pages (from-to)	3183-3187
Number of pages	5
Journal	Inorganic Chemistry
Volume	35
Issue number	11
DOIs	https://doi.org/10.1021/ic950580e
State	Published - 1996

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@article{7dd5c140f88f4d53b657419366a4b60c,

title = "Transition metal complexes of cyanoisocyanoarenes as building blocks for one-, two-, and three-dimensional molecular solids",

abstract = "The complexes trans-[MI2(CNC6H4-CN-4)2]< (M = Pd and Ft), trans-[FeI2L4] (L = CNC6H4-CN-4 and CNC6H2-Me2-2.6-CN-4), and [Mn(CNC6H4-CN-4)6][SO3CF 3] were prepared. The compounds are thermally stable up to 230 °C or higher. The molecular structure of trans-[FeI2(CNC6H4-CN-4)4] was determined by X-ray crystallography: monoclinic, space group P21/n, a = 11.570(2) {\AA}, b = 10.1052(8) {\AA}, c = 28.138(7) {\AA}, β= 92.034(9)°, Z = 4, 3464 unique reflections, R = 0.074, Rw = 0.089. The complexes contain the peripheral cyano groups in linear, planar, and octahedral dispositions, respectively. Solids were obtained by combining solutions of [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2], [FeI2CNC6H4-CN-44)] and AgSO3CF3, [FeI2(CNC6H2-Me2-2,6-CN-4) 4] and [Rh2(O2CCF3)4], and [Mn(CNC6H4-CN-4)6][SO3CF 3] and [Rh2(O2CCF3)4]. [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2] in a ratio of 1:2 form a crystalline, one-dimensional solid: monoclinic, space group P21/c, a = 8.317(2) {\AA}, b = 13.541(1) {\AA}, c = 22.568(5) {\AA} β= 100.45(1)°, Z = 2, 3279 unique reflections, R = 0.037, Rw = 0.047.",

author = "Mao, \{Li Feng\} and Andreas Mayr",

year = "1996",

doi = "10.1021/ic950580e",

language = "English",

volume = "35",

pages = "3183--3187",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "11",

}

TY - JOUR

T1 - Transition metal complexes of cyanoisocyanoarenes as building blocks for one-, two-, and three-dimensional molecular solids

AU - Mao, Li Feng

AU - Mayr, Andreas

PY - 1996

Y1 - 1996

N2 - The complexes trans-[MI2(CNC6H4-CN-4)2]< (M = Pd and Ft), trans-[FeI2L4] (L = CNC6H4-CN-4 and CNC6H2-Me2-2.6-CN-4), and [Mn(CNC6H4-CN-4)6][SO3CF 3] were prepared. The compounds are thermally stable up to 230 °C or higher. The molecular structure of trans-[FeI2(CNC6H4-CN-4)4] was determined by X-ray crystallography: monoclinic, space group P21/n, a = 11.570(2) Å, b = 10.1052(8) Å, c = 28.138(7) Å, β= 92.034(9)°, Z = 4, 3464 unique reflections, R = 0.074, Rw = 0.089. The complexes contain the peripheral cyano groups in linear, planar, and octahedral dispositions, respectively. Solids were obtained by combining solutions of [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2], [FeI2CNC6H4-CN-44)] and AgSO3CF3, [FeI2(CNC6H2-Me2-2,6-CN-4) 4] and [Rh2(O2CCF3)4], and [Mn(CNC6H4-CN-4)6][SO3CF 3] and [Rh2(O2CCF3)4]. [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2] in a ratio of 1:2 form a crystalline, one-dimensional solid: monoclinic, space group P21/c, a = 8.317(2) Å, b = 13.541(1) Å, c = 22.568(5) Å β= 100.45(1)°, Z = 2, 3279 unique reflections, R = 0.037, Rw = 0.047.

AB - The complexes trans-[MI2(CNC6H4-CN-4)2]< (M = Pd and Ft), trans-[FeI2L4] (L = CNC6H4-CN-4 and CNC6H2-Me2-2.6-CN-4), and [Mn(CNC6H4-CN-4)6][SO3CF 3] were prepared. The compounds are thermally stable up to 230 °C or higher. The molecular structure of trans-[FeI2(CNC6H4-CN-4)4] was determined by X-ray crystallography: monoclinic, space group P21/n, a = 11.570(2) Å, b = 10.1052(8) Å, c = 28.138(7) Å, β= 92.034(9)°, Z = 4, 3464 unique reflections, R = 0.074, Rw = 0.089. The complexes contain the peripheral cyano groups in linear, planar, and octahedral dispositions, respectively. Solids were obtained by combining solutions of [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2], [FeI2CNC6H4-CN-44)] and AgSO3CF3, [FeI2(CNC6H2-Me2-2,6-CN-4) 4] and [Rh2(O2CCF3)4], and [Mn(CNC6H4-CN-4)6][SO3CF 3] and [Rh2(O2CCF3)4]. [PdI2(CNC6H4-CN-4)2] and [Cu(hfacac)2] in a ratio of 1:2 form a crystalline, one-dimensional solid: monoclinic, space group P21/c, a = 8.317(2) Å, b = 13.541(1) Å, c = 22.568(5) Å β= 100.45(1)°, Z = 2, 3279 unique reflections, R = 0.037, Rw = 0.047.

UR - https://www.scopus.com/pages/publications/0001513902

U2 - 10.1021/ic950580e

DO - 10.1021/ic950580e

M3 - Article

AN - SCOPUS:0001513902

SN - 0020-1669

VL - 35

SP - 3183

EP - 3187

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Transition metal complexes of cyanoisocyanoarenes as building blocks for one-, two-, and three-dimensional molecular solids

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