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Understanding negative thermal expansion and 'trap door' cation relocations in zeolite rho

  • B. A. Reisner
  • , Y. Lee
  • , J. C. Hanson
  • , G. A. Jones
  • , J. B. Parise
  • , D. R. Corbin
  • , B. H. Toby
  • , A. Freitag
  • , J. Z. Larese
  • , V. Kahlenberg
  • Stony Brook University

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

In situ time-resolved synchrotron X-ray and neutron powder diffraction studies indicate that the negative thermal expansion and 'trap door' cation relocations observed in zeolite rho result from water-mediated chemical changes that occur during dehydration.

Original languageEnglish
Pages (from-to)2221-2222
Number of pages2
JournalChemical Communications
Issue number22
DOIs
StatePublished - Nov 21 2000

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