Vibrational study of enriched13 C60 crystals

Michael C. Martin; J. Fabian; J. Godard; P. Bernier; J. M. Lambert; L. Mihaly

doi:10.1103/PhysRevB.51.2844

Vibrational study of enriched13 C60 crystals

Michael C. Martin
, J. Fabian
, J. Godard
, P. Bernier
, J. M. Lambert
, L. Mihaly

Physics and Astronomy

Stony Brook University
Laboratoire de Physique des Solides
Université de Montpellier

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes. Symmetry breaking due to C13 isotopes provides a possible route for optically activating IR-silent vibrational modes. Experimental spectra and a semiempirical theory on natural abundance and enriched13 single crystals of C60 are presented. By comparing the experimental results with the theoretical results, we exclude this isotopic activation mechanism from the explanation for weakly active fundamentals in the spectra.

Original language	English
Pages (from-to)	2844-2847
Number of pages	4
Journal	Physical Review B
Volume	51
Issue number	5
DOIs	https://doi.org/10.1103/PhysRevB.51.2844
State	Published - 1995

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@article{19592b0032ef44fc8d5273580aee3008,

title = "Vibrational study of enriched13 C60 crystals",

abstract = "The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes. Symmetry breaking due to C13 isotopes provides a possible route for optically activating IR-silent vibrational modes. Experimental spectra and a semiempirical theory on natural abundance and enriched13 single crystals of C60 are presented. By comparing the experimental results with the theoretical results, we exclude this isotopic activation mechanism from the explanation for weakly active fundamentals in the spectra.",

author = "Martin, \{Michael C.\} and J. Fabian and J. Godard and P. Bernier and Lambert, \{J. M.\} and L. Mihaly",

year = "1995",

doi = "10.1103/PhysRevB.51.2844",

language = "English",

volume = "51",

pages = "2844--2847",

journal = "Physical Review B",

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TY - JOUR

T1 - Vibrational study of enriched13 C60 crystals

AU - Martin, Michael C.

AU - Fabian, J.

AU - Godard, J.

AU - Bernier, P.

AU - Lambert, J. M.

AU - Mihaly, L.

PY - 1995

Y1 - 1995

N2 - The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes. Symmetry breaking due to C13 isotopes provides a possible route for optically activating IR-silent vibrational modes. Experimental spectra and a semiempirical theory on natural abundance and enriched13 single crystals of C60 are presented. By comparing the experimental results with the theoretical results, we exclude this isotopic activation mechanism from the explanation for weakly active fundamentals in the spectra.

AB - The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes. Symmetry breaking due to C13 isotopes provides a possible route for optically activating IR-silent vibrational modes. Experimental spectra and a semiempirical theory on natural abundance and enriched13 single crystals of C60 are presented. By comparing the experimental results with the theoretical results, we exclude this isotopic activation mechanism from the explanation for weakly active fundamentals in the spectra.

UR - https://www.scopus.com/pages/publications/0011648213

U2 - 10.1103/PhysRevB.51.2844

DO - 10.1103/PhysRevB.51.2844

M3 - Article

AN - SCOPUS:0011648213

SN - 0163-1829

VL - 51

SP - 2844

EP - 2847

JO - Physical Review B

JF - Physical Review B

IS - 5

ER -

Vibrational study of enriched13 C60 crystals

Abstract

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