X-ray diffraction studies on cis-[Ru(bpy)2(PMe3)Cl+][ClO4-] and cis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO 4-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

Melvyn Rowen Churchill; Lynn M. Krajkowski; My Hang Vo Huynh; Kenneth J. Takeuchi

doi:10.1007/BF02576457

X-ray diffraction studies on cis-[Ru(bpy)₂(PMe₃)Cl⁺][ClO₄-] and cis-[Ru(bpy)₂{PMe₂(o-tol)}Cl⁺][ClO ₄^-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

Melvyn Rowen Churchill
, Lynn M. Krajkowski
, My Hang Vo Huynh
, Kenneth J. Takeuchi

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The complex cis-[Ru(bpy)₂(PMe₃)Cl⁺][ClO₄ ^-] crystallizes in space group P2₁/c and cis-[Ru(bpy)₂{PMe₂(o-tol)]Cl⁺][ClO ₄^-] crystallizes in space group P1̄; each is present as a racemate and neither structure suffers from disorder. The Ru-PMe₂(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru-PMe₃ bond length of 2.310(2)Å.

Original language	English
Pages (from-to)	589-597
Number of pages	9
Journal	Journal of Chemical Crystallography
Volume	27
Issue number	10
DOIs	https://doi.org/10.1007/BF02576457
State	Published - Oct 1997

Keywords

Bipyridyl
Crystal structure
Dimethyl(o-tolyl)phosphine
Hydrogen bonding
Ruthenium(II) complex
Trimethylphosphine

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10.1007/BF02576457

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@article{3f059e681f0f438b922e3e080ffb8051,

title = "X-ray diffraction studies on cis-[Ru(bpy)2(PMe3)Cl+][ClO4-] and cis-[Ru(bpy)2\{PMe2(o-tol)\}Cl+][ClO 4-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series",

abstract = "The complex cis-[Ru(bpy)2(PMe3)Cl+][ClO4 -] crystallizes in space group P21/c and cis-[Ru(bpy)2\{PMe2(o-tol)]Cl+][ClO 4-] crystallizes in space group P{\=1}; each is present as a racemate and neither structure suffers from disorder. The Ru-PMe2(o-tol) bond length of 2.324(2){\AA} is slightly longer than the simple Ru-PMe3 bond length of 2.310(2){\AA}.",

keywords = "Bipyridyl, Crystal structure, Dimethyl(o-tolyl)phosphine, Hydrogen bonding, Ruthenium(II) complex, Trimethylphosphine",

author = "Churchill, \{Melvyn Rowen\} and Krajkowski, \{Lynn M.\} and Huynh, \{My Hang Vo\} and Takeuchi, \{Kenneth J.\}",

year = "1997",

month = oct,

doi = "10.1007/BF02576457",

language = "English",

volume = "27",

pages = "589--597",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "10",

}

X-ray diffraction studies on cis-[Ru(bpy)₂(PMe₃)Cl⁺][ClO₄-] and cis-[Ru(bpy)₂{PMe₂(o-tol)}Cl⁺][ClO ₄^-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series. / Churchill, Melvyn Rowen; Krajkowski, Lynn M.; Huynh, My Hang Vo et al.
In: Journal of Chemical Crystallography, Vol. 27, No. 10, 10.1997, p. 589-597.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-ray diffraction studies on cis-[Ru(bpy)2(PMe3)Cl+][ClO4-] and cis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO 4-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

AU - Churchill, Melvyn Rowen

AU - Krajkowski, Lynn M.

AU - Huynh, My Hang Vo

AU - Takeuchi, Kenneth J.

PY - 1997/10

Y1 - 1997/10

N2 - The complex cis-[Ru(bpy)2(PMe3)Cl+][ClO4 -] crystallizes in space group P21/c and cis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO 4-] crystallizes in space group P1̄; each is present as a racemate and neither structure suffers from disorder. The Ru-PMe2(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru-PMe3 bond length of 2.310(2)Å.

AB - The complex cis-[Ru(bpy)2(PMe3)Cl+][ClO4 -] crystallizes in space group P21/c and cis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO 4-] crystallizes in space group P1̄; each is present as a racemate and neither structure suffers from disorder. The Ru-PMe2(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru-PMe3 bond length of 2.310(2)Å.

KW - Bipyridyl

KW - Crystal structure

KW - Dimethyl(o-tolyl)phosphine

KW - Hydrogen bonding

KW - Ruthenium(II) complex

KW - Trimethylphosphine

UR - https://www.scopus.com/pages/publications/0031325513

U2 - 10.1007/BF02576457

DO - 10.1007/BF02576457

M3 - Article

AN - SCOPUS:0031325513

SN - 1074-1542

VL - 27

SP - 589

EP - 597

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 10

ER -

X-ray diffraction studies on cis-[Ru(bpy)₂(PMe₃)Cl⁺][ClO₄-] and cis-[Ru(bpy)₂{PMe₂(o-tol)}Cl⁺][ClO ₄^-]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

Abstract

Keywords

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